Presentation Details
High Spatial Resolution Mapping of Urbach Energy in Photovoltaic Devices

Jacques D Kenyon, Kieran M Curson, Xiaolei Liu, Aoshi Yang, Lukša Kujović, Stuart Robertson, Zhaoxia Zhou, Jake W Bowers, John M Walls.

Loughborough University, Loughborough, United Kingdom

Abstract


This work comprises of modelling a fundamental property of semiconductors known as Urbach Energy, indicating energetic disorder at a high resolution/nanoscale using Cathodoluminescence, to bridge the gap between understanding the influence of structural variation and disorder upon recombination behaviour. Mapping/spatially resolving Urbach energy on cross-sectional images of semiconductors used as PV absorbing materials provides an understanding into which fabrication processes and techniques are most detrimental to device performance, and what techniques can help restore it. Examples presented in this work show how structural and elemental variations influence disorder differently, such as grain boundary types, elemental clustering and grading, and stacking fault behaviour.

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