Presentation Details
Efficiency Improvement of Cu3BiS3 Thin Film Solar Cell using NiO Hole Transport Layer

Sandip Das, .

Kennesaw State University, Marietta, GA, USA

Abstract


Cu₃BiS₃ has gained attention as a promising absorber for low-cost, environmentally benign, and earth-abundant thin-film photovoltaic technologies. In this study, we investigate the performance improvement of Cu₃BiS₃ solar cells through the incorporation of NiO as a hole transport material (HTM). Numerical simulations using SCAPS-1D demonstrate that the solar cell structure including a 200 nm thick NiO layer at the rear contact outperforms the conventional cell without a NiO. The proposed heterojunction solar cell architecture, with an Al/ITO/ZnO/CdS/Cu₃BiS₃/NiO/Mo/SLG structure achieved an open-circuit voltage of 586 mV and a power conversion efficiency of 11.15% under AM1.5 irradiance with only 1.0 µm-thick absorber layer. These values correspond to an approximately 17% increase in short-circuit current density and approximately 22% improvement in efficiency compared to the reference cell. The findings highlight that NiO or other similar HTMs can significantly boost the efficiency of thin film Cu₃BiS₃-based heterojunction solar cells.

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